For one thing, 35mm film resolution is equivalent to about 2000x1500 pixels, whereas VHS is equivalent to about 320x480 pixels: worse, VHS color resolution is maybe 1/4 of that.
As for film vs video, one of the main issues is that film handles a much higher contrast range than video: hence if you shoot the same scene on film and video, on film you'll still get detail in the highlights and shadows when on video the highlights are pure white and the shadows are pure black. I read an article a few months ago with actual numbers for typical film, HD and DV contrast ranges, but forget what they were.